Research Highlight

The Wang Group: Heterogenous catalysis

Surface Bound Iridium Catalysts

“End-on Bound Ir Dinuclear Heterogeneous Catalysts on WO3 for Solar Water Oxidation,” ACS Central Sci. 2018, 4, 1166-1172

Fig. 1.


“Stable Iradium Dinuclear Heterogeneous Catalysts Supported by Metal Oxide Substrate for Solar Water Oxidation,” Proc. Nat. Acad. Sci. 2018, 115, 2902-2907Lithium-oxygen battery:

Our group developed a facile photochemical way to synthesize Iridium dinuclear heterogeneous catalyst (DHCs) and for the first-time report that both side-on and end-on binding are possible for Ir DHCs supported on different substrates. Our finding is built upon recent advances aimed at studying single-atom catalysts (SACs) but takes a crucial step forward. It provides a great material platform to study reactions that would require more than one active site.

Lithium Ion Batteries


“Cathodically Stable Li-O2 Battery Operations Using Water-in-Salt Electrolyte,” Chem 2018, 4, 1345-1358


“Stable Multimetallic Nanoparticles for Oxygen Electrocatalysis,” Nano Lett. 2019, 19, 5149

Development of the Li-O2 battery as a practical energy storage technology has been underpinned by the lack of a stable electrolyte to enable reversible conversion between O2 and Li2O2, given that previous applied organic electrolytes all show reactivity toward reactive oxygen species. Our group demonstrates that this issue can be solved with a water-in-salt electrolyte that contains no organic solvent molecules. The net result is a highly effective electrolyte that enables stable Li-O2 battery operations up to 300 cycles.

Previous
Group Highlight: Prof. Alexander Miller
The Miller Group: Organometallic chemistry
Group Highlight: Prof. Dunwei Wang
The Wang Group: Heterogenous catalysis
Group Highlight: Prof . Chong Liu
The Liu Group: Electrochemical interfaces
Group Highlight: Prof. Jeffrey A. Byers
The Byers Group: Organometallic chemistry
Group highlight: Prof. Paula Diaconescu
The Diaconescu Group: Redox switchable catalysis
Group Highlight: Prof. Loi Do
The Loi Do’s group: organometallic chemistry of olefin polymerization